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By P. W. Anderson

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Danielson, unpublished. W. Kaenzig, Phys. Rev. 80, 94 (1950). / 4. Fig. 4: I t as a function of temperature in BaTiC>3. tions add up to zero polarization for the specimen as a whole. Through beautiful theoretical and experimental work3 the domains in ferromagnets have come in quite recent years to be understood and definitely "pinned down" theoretically, as well as made visible experimentally with the powder pattern technique. The opposite order is the rule in ferroelectrics: the domains are easily visible and, in some cases, have been the first observed evidence of ferro-electricity: it has been easier to identify a ferroelectric optically by looking for domains than electrically by finding a hysteresis loop — although the latter, it must be said, is a far surer test, since domain-like twinning is found to be surprisingly common.

5: Crystal structure of BaTiC>3. 23 er two shortening, to become the c and a axes respectively of the tetragonal structure. 01 at room temperature. 044 A in the direction of the c-axis, the O ions moving very slightly the other way4. This is confirmed by the fact that the spontaneous polarization P s has been found, by experiments on single crystals, to lie along the c-axis. It is fairly certain that the positively-charged Ti ions move in the direction of P s and the negative O ions in the opposite direction.

Interesting, but not, apparently, significant. The second type of experimental data available is that on the relative breadths for all the lines in the B. 20 Band Spectra In Table II we present our theoretical results on relative 21 16 Lindholm ' has taken a great deal of experimental values. In order to avoid the ambiguity due to the interpolation procedure, we have normalized the theo- data on line-breadths in the vibrational bands of HC1 retical value for the 33 line to fit the experimental value and HCN.

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